Engineering Physics II - Ch. 6.6

Q.12.      Define drift velocity, mobility and conductivity of a semiconductors. Obtain an expression for the electrical conductivity of an intrinsic semiconductor.(AKTU. 2015 - 16)       
Ans.        Drift Velocity: -
                                The drift velocity is the average velocity that a particle, such as an electron, attains in a material due to an electric field. It can also be referred to as axial drift velocity. In general, an electron will propagate randomly in a conductor at the Fermi velocity. An applied electric field will give this random motion a small net flow velocity in one direction.
                In a semiconductor, the two main carrier scattering mechanisms are ionized impurity scattering and lattice scattering.
                Because current is proportional to drift velocity, which in a resistive material is, in turn, proportional to the magnitude of an external electric field, Ohm's law can be explained in terms of drift velocity.
                The most elementary expression of Ohm's law is:
                u = mE
where u is the drift velocity, ยต is the electron mobility (with units m2/(V·s)) of the material and E is the electric field (with units V/m).
Electron Mobility: -
                In solid-state physics, the electron mobility characterizes how quickly an electron can move through a metal or semiconductor, when pulled by an electric field. In semiconductors, there is an analogous quantity for holes, called hole mobility. The term carrier mobility refers in general to both electron and hole mobility in semiconductors.
                Electron and hole mobility are special cases of electrical mobility of charged particles in a fluid under an applied electric field.
                Conductivity is proportional to the product of mobility and carrier concentration. For example, the same conductivity could come from a small number of electrons with high mobility for each, or a large number of electrons with a small mobility for each. For metals, it would not typically matter which of these is the case, since most metal electrical behavior depends on conductivity alone. Therefore mobility is relatively unimportant in metal physics. On the other hand, for semiconductors, the behavior of transistors and other devices can be very different depending on whether there are many electrons with low mobility or few electrons with high mobility. Therefore mobility is a very important parameter for semiconductor materials. Almost always, higher mobility leads to better device performance, with other things equal.     
Electrical Conductivity Of An Intrinsic Semiconductor: -
                When an electric field is applied across an intrinsic semiconductor, in addition to the thermal motion, the free electrons and holes exhibit a steady drift constituting a current flow.
                The current density contributed by electron flow is given by
                                jn = nevn                                                                          ...............(i)                   
where e is the charge of electron and vn is the drift velocity free electrons.
                The current density contributed by hole flow is given by
                                jp = pevp                                                                          ...............(ii)
where vp is the drift velocity of the holes. 
                Then, the conductivity due to electrons is given by
                                                                                ...............(iii)
Where E is the applied electric field and  is the mobility of free electrons defined as the drift velocity of electrons when subjected to unit electric field.
Similarly, the conductivity due to the holes is given by
                                                                              ...............(iv)
where  is the mobility of  holes.
As both electrons and holes contribute to current flow in an intrinsic semiconductor, the total conductivity in an intrinsic semiconductor is given as
                                si = sn + sp = eni(mn + mp)                                      ...............(v)

where si is called the intrinsic conductivity.